Guia docente 2014_15 Facultad de Química

Contents

Topic	Sub-topic
(*)Electromagnetic field: Maxwell's equations	(*)
(*)Quantum theory of radiation. Wave-particle duality.	(*)Ultraviolet Catastrophe. Fotoelectric Effect. X Rays. Bragg's condition. Compton Effect. Wave-particle duality.
(*)Principles of Quantum Chemistry	(*)Limitations of Clasic Physics and origin of Quantum Mechanics. De Broglie's Hypothesis. Uncertainty Principles. Quantum Mechanics Postulates. Virial Theorem.
(*)Simple Models of Quantum Chemistry	(*)Introduction Particle in a Box Harmonic Oscillator Angular Momentum and Rigid Rotor
(*)Approximation Methods in Quantum Mechanics	(*)Introducción. Variational Method. Perturbational Method.
(*)Hydrogen-like atoms	(*)Introduction. Radial Part of Schrödinger's Equation. Hydrogen-like Atomic Orbitals. Electronic Spin. Spin-Orbit Coupling. Hyperfine Structure. Atomic Hydrogen Spectrum.
(*)Polielectronic Atoms	(*)Model of Independent Electrons. Antisymmetry Principle. SCF-HF Method. Electronic terms and levels. Polielectronic Atoms Spectra.
(*)Statistical Mechanics	Nomenclatura y postulados. Colectivo canónico. Función de partición canónica para un sistema de partículas no interaccionantes. Ley de distribución de Boltzmann para partículas no interaccionantes. Términos de la función de partición de un gas ideal. Termodinámica estadística de gases ideales. Termodinámica estadística de sistemas reales: fuerzas intermoleculares e integral de configuración.