Guia docente 2023_24
Centro Universitario da Defensa da Escola Naval Militar de Marín
Grado en Ingeniería Mecánica
 Subjects
  Chemistry: Chemistry
   Contents
Topic Sub-topic
UNIT 1 (U1): ELEMENTAL CHEMISTRY (8 hours) U1-1. ATOMIC THEORY AND STRUCTURE OF MATTER (3 hours)

Introduction to the atomic structure.
Structures periodicity.
Atom characteristics: Atomic number and atomic mass. Isotopes.
Periods and groups. Mendeleev's classification.
Periodicity of the properties: atomic volume, ionization energy, electronic affinity and electronegativity.
Nuclear chemistry.

U1-2. CHEMICAL BONDING (3 hours)

Introduction to chemical bonding.
Covalent bond: Lewis notation.
Valence bond theory.
Ionic bond.
Metallic bond.

U1-3. AGGREGATION STATES (2 hours)

Gaseous State: Ideal Gases, Real Gases.
Intermolecular forces.
Liquid State: Characteristics of liquids. Surface tension and viscosity.
State changes: Fusion, evaporation and sublimation.
Solutions: Mechanism, classification and colligative properties.
Solubility of gases in liquids. Colloidal mixtures.
Solid state: Melting points, phase diagrams. Properties of solids.
UNIT 2 (U2): REACTIONS AND CHEMICAL PROCESSES (18 hours) U2-1 CHEMICAL REACTIONS (I) (12 hours)

Stoichiometric aspects.
Energy aspects: thermochemistry.
Kinetic aspects.
Introduction to chemical equilibrium.
Acid-base reactions and pH
Equilibrium of solubility.

U2-2 CHEMICAL REACTIONS (II) (6 hours)

Redox reactions.
Applied electrochemistry: batteries and potential.
Corrosion and surface treatment.
Electrochemical sensors.
UNIT 3 (U3) INTRODUCTION TO INDUSTRIAL CHEMISTRY (2 hours) U3-1 INTRODUCTION TO CHEMICAL ENGINEERING (1 hour)

Basic concepts of Chemical Engineering.
Instrumentation and analysis in Chemical Engineering.

U3-2 CHEMICAL INDUSTRY. INORGANIC AND ORGANIC CHEMISTRY (1 hour)

Basic Principles of Organic and Inorganic Chemistry.
Oil and derivatives: Petrochemistry.
Coal: Carbochemistry.
PRACTICES OF LABORATORY (14 hours)

includes in this epigraph the realisation of a project.
PL1. CHEMICAL BALANCE: LE CHATELIER´S PRINCIPLE

Two reversible reactions will be studied, that have the advantage of the great ease with which the presence of reactants and products are detected, caused by color changes or by the appearance of a precipitate.

PL2. ACID-BASE TITRATION: TITRATION CURVE

Acid-base titrations are very useful to accurately determine the concentration of an acid/basic solution by adding a base or an acid of known concentration. Specifically, the assessment of a strong base with a strong acid will be carried out, for which different amounts of acid will be added and the pH of the resulting solution will be measured. In this way, the corresponding "titration curve" will be obtained and the pertinent conclusions will be drawn.

PL3. REDOX AND ELECTROCHEMICAL PROCESSES: ELECTROLYSIS

In order to become familiar with the chemical changes induced by an electric current and with the quantitative relationships involved, students will carry out the following experiences: Electrolysis of aqueous CuSO4(aq) and electrolysis of NaCl(aq).

PROJECT

Five laboratory sessions will be dedicated to the project, with the following estimated distribution:

P1. Presentation of the project: Proposal for treatment systems for ballast water.
P2-3 Experimental work in the laboratory.
P4 Preparation of the report-
P5 Presentation of the results.
SEMINARS (7 hours)

The planning of the seminars will correspond to the development of theory and laboratory classes.

S1. Atomic theory and bonding
S2. Aggregation states
S3. Termochemistry
S4. Chemical equilibrium
S5. Acid-base
S6. Solubility
S7. Redox
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