| Topic |
Sub-topic |
| Subject 1: Introduction to the Chemistry of the transition metals. |
Physical properties.
Electronic configuration. multielectronic systems Spectroscopic terms.
Reactivity and properties |
| Subject 2: Coordination chemistry. |
Coordination numbers and geometries.
Type of ligands.
Isomers in coordination chemistry.
Nomenclature. |
| Subject 3: Bonding in the coordination compounds (I): |
Crystal field theory.
Weak and strong field complexes in octahedral complexes.
Tetrahedral square-plane complexes. |
| Subject 4: Bonding in the coordination compounds (II): |
Molecular orbital theory in octahedral complexes.
The metal-ligand interaction. |
| Subject 5: Spectroscopical and magnetic properties in metal complexes. |
Energy states.
Selection rules.
Charateristics of the electronic spectra,
Magnetic behavior. |
| Subject 6: Thermodinamic properties of the coordination compounds. |
Stability constants and and factors that afect tthem. Chelate, macrocycle and criptate effect. |
| Subject 7: Mechanisms of reaction in coordination compounds. |
Substitution reactions of *sustitución in square-plane and octahedral complexes.
Electronic transfe. |
| Subject 8: Chemistry of the transitional metals |
Global aspects.
Frost diagrams.
General methods of obtention and purification of the metals. |
| Subject 9: Chemistry of the 3 and 5 groups metáls. |
Extraction and uses.
Oxidation states.
Representative compounds of titanium: halides, oxides and mixed oxides.
Coordination Compounds. |
| Subject 10: Chemistry of the 5 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of vanadium: halides, oxides and oxoanions.
Coordination Compounds. |
| Subject 11: Chemistry of the 6 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of chromium: halides, oxides and oxoanions.
Coordination Compounds. |
| Subject 12: Chemistry of the 7 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of manganese: halides, oxides and oxoanions.
Coordination Compounds.
Bioinorganic chemistry of the manganese and technetium. |
| Subject 13: Chemistry of the 8 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of iron: halides, oxides and mixture oxides.
Coordination Compounds.
Bioinorganic chemistry of iron. |
| Subject 14: Chemistry of the 9 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of cobalt: halides, oxides and coordination compounds.
Bioinorganic chemistry of cobalt. |
| Subject 15: Chemistry of the 10 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of nickel: halides, oxides and coordination compounds.
Bioinorganic chemistry of platinum. |
| Subject 16: Chemistry of the 11 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of copper: halides, óxides and coordination compounds.
Bioinorganic chemistry of copper and gold. |
| Subject 17: Chemistry of the 12 group metals. |
Extraction and uses.
Oxidation states.
Representative compounds of zinc and mercury: halides, oxides and coordination compounds.
Bioinorganic chemistry of the elements of the group. |
